Coordination CompoundshardMCQ SINGLE

Which of the following chemical formulas corresponds to the IUPAC name 'dibromidobis(ethylenediamineCoordination Compounds Chemistry Question

Question

Which of the following chemical formulas corresponds to the IUPAC name 'dibromidobis(ethylenediamine)chromium(III) bromide'?

Answer: A

💡 Solution & Explanation

1. The complex cation has the ligands 'dibromido' ($2$ $Br^-$) and 'bis(ethylenediamine)' ($2$ $en$). 2. The central metal is chromium with an oxidation state of $+3$. 3. The cation formula is $[Cr(en)_2Br_2]^{n+}$. To find the charge $n$: $n = +3 (\text{from } Cr) + 2(0) (\text{from } en) + 2(-1) (\text{from } Br) = +1$. 4. To balance the $+1$ charge, exactly one bromide ($Br^-$) counter ion is needed outside the sphere. 5. The complete formula is $[Cr(en)_2Br_2]Br$.

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