Which of the following sequences accurately represents the increasing order of bond dissociation ent β Chemical Bonding Chemistry Question
Question
Which of the following sequences accurately represents the increasing order of bond dissociation enthalpy for halogen molecules?
Answer: C
π‘ Solution & Explanation
Generally, bond dissociation enthalpy decreases as atomic size increases. However, $F_2$ exhibits an exceptionally low bond dissociation energy (lower than $Cl_2$ and $Br_2$) due to immense inter-electronic repulsions between the lone pairs localized on the very small fluorine atoms. Thus, the order is $I_2 < F_2 < Br_2 < Cl_2$.
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