The trifluoromethyl group () is a powerful meta-director. Which of the following statements explain — Aromatic Hydrocarbons Chemistry Question
Question
The trifluoromethyl group ($-CF_3$) is a powerful meta-director. Which of the following statements explain this observation based on arenium ion stability?
Answer: B,C
💡 Solution & Explanation
The $-CF_3$ group is strongly electron-withdrawing due to the high electronegativity of fluorine ($-I$ effect). If an electrophile attacks ortho or para, one of the resulting resonance structures places a positive charge directly on the ring carbon attached to the already partially positive $-CF_3$ carbon, which is highly unstable due to electrostatic repulsion. Meta attack avoids this highly destabilizing structure.
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