Which of the following factors specifically contribute to the highly endothermic nature of the first — Aromatic Hydrocarbons Chemistry Question
Question
Which of the following factors specifically contribute to the highly endothermic nature of the first step (formation of the arenium ion) in a general electrophilic aromatic substitution?
Answer: A,B,C
💡 Solution & Explanation
The first step involves breaking the cyclic, delocalized $6\pi$ electron system (resulting in the loss of resonance energy), changing the hybridization of one carbon to $sp^3$, and creating a charged intermediate. The $C-H$ bond is NOT broken in the first step; it is broken in the second (fast, exothermic) step.
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