Regarding the distinguishing oxidation tests for carbonyl compounds, which of the following statemen β Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
Regarding the distinguishing oxidation tests for carbonyl compounds, which of the following statements are chemically accurate?
Answer: A,C,D
π‘ Solution & Explanation
Aldehydes reduce the $Cu^{2+}$ in Benedict's (citrate complex) and Fehling's (tartrate complex) to $Cu_2O$ (red ppt). The Haloform test is positive for methyl ketones and alcohols oxidizable to methyl ketones. Tollen's involves $Ag^+$ reduction. Popoff's rule actually states the carbonyl group stays with the *smaller* alkyl chain, making statement B false.
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