Which of the following reagents selectively oxidizes the active methylene ( -carbon) adjacent to a c — Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
Which of the following reagents selectively oxidizes the active methylene ($\alpha$ -carbon) adjacent to a carbonyl group to yield a 1,2-dicarbonyl compound, without breaking the carbon skeleton?
Answer: B
💡 Solution & Explanation
Selenium dioxide ($SeO_2$) is a highly specific oxidizing agent that oxidizes an $\alpha$ -methylene ($-CH_2-$) or $\alpha$ -methyl ($-CH_3$) group adjacent to a carbonyl group into a second carbonyl group ($>C=O$), forming a dicarbonyl compound. $KMnO_4$ and $HNO_3$ cause oxidative cleavage of the carbon skeleton.
💬Ask on WhatsApp →
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp — gets answered in minutes