Aldehydes Ketones and Carboxylic AcidshardNUMERICAL

Vapours of pure acetic acid () are passed over heated catalyst at to yield a principal carbonyl compAldehydes Ketones and Carboxylic Acids Chemistry Question

Question

Vapours of pure acetic acid ($CH_3COOH$) are passed over heated $MnO$ catalyst at $300^\circ C$ to yield a principal carbonyl compound. What is the total number of $\alpha$ -hydrogens present in one molecule of this principal product?

Answer: 6

💡 Solution & Explanation

Passing acetic acid vapours over $MnO/300^\circ C$ induces bimolecular decarboxylative condensation: $2 CH_3COOH \rightarrow CH_3COCH_3 + CO_2 + H_2O$. The product is Acetone, which possesses two methyl groups attached to the carbonyl, giving $3 + 3 = 6$ $\alpha$ -hydrogens.

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