Thermal decarboxylation usually yields saturated products or ketones, but one specific class of subs — Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
Thermal decarboxylation usually yields saturated products or ketones, but one specific class of substituted carboxylic acids decarboxylates on heating to give alkenes. Which of the following is it?
Answer: C
💡 Solution & Explanation
While gem-dicarboxylic acids and $\beta$ -keto acids decarboxylate to form alkanes/ketones respectively, $\beta,\gamma$ -unsaturated acids uniquely undergo decarboxylation on heating to yield alkenes via a concerted mechanism.
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