Alcohols Phenols and EthersmediumMCQ SINGLE⭐ Must-Do

Aniline can be converted into phenol via a stable intermediate diazonium salt. Which of the followinAlcohols Phenols and Ethers Chemistry Question

Question

Aniline can be converted into phenol via a stable intermediate diazonium salt. Which of the following specifies the correct reagents and the critical temperature range for the initial diazotization step?

Answer: C

💡 Solution & Explanation

A diazonium salt is formed by treating an aromatic primary amine (aniline) with nitrous acid ($HNO_2$, generated in situ from $NaNO_2 + HCl$) strictly at ice-cold temperatures ($273-278\text{ K}$ or $0-5^\circ\text{C}$). Higher temperatures cause premature decomposition. The salt is then warmed with water to yield phenol.

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