Alcohols Phenols and EthershardMCQ MULTIPLE

The Lucas test is utilized to differentiate classes of alcohols based on their reactivity kinetics wAlcohols Phenols and Ethers Chemistry Question

Question

The Lucas test is utilized to differentiate classes of alcohols based on their reactivity kinetics with a mixture of $HCl$ and $ZnCl_2$. Which of the following statements regarding this laboratory test are correct?

Answer: A,B,D

💡 Solution & Explanation

Turbidity is caused by the insolubility of the resulting alkyl halide. Benzyl and allyl alcohols form highly resonance-stabilized carbocations, causing them to react very rapidly via an $S_N1$ mechanism, much like tertiary alcohols. Statement C is incorrect because tertiary alcohols react via an $S_N1$ mechanism (carbocation intermediate), not $S_N2$. Primary alcohols are too unreactive to form turbidity at room temperature.

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