X --(Ξ, conc. H3PO4)--> Yβ ; Yβ --(FeCl3 vapour)--> Zβ (coloured vapours) ; Yβ --(AgNO3)--> Qβ (solu β Qualitative and Quantitative Analysis Chemistry Question
Question
X --(Ξ, conc. H3PO4)--> Yβ ; Yβ --(FeCl3 vapour)--> Zβ (coloured vapours) ; Yβ --(AgNO3)--> Qβ (soluble in excess conc. NH3 soln.). Which of the following anion cannot be in X ?
π‘ Solution & Explanation
Step 1: When NaOH is added to the mixture containing Al3+, Zn2+, and Cu2+, all of them initially form hydroxide precipitates. Step 2: Since Al(OH)3 and Zn(OH)2 are amphoteric, they dissolve in excess NaOH to form soluble aluminate ([Al(OH)4]-) and zincate ([Zn(OH)4]2-) complexes. Step 3: In contrast, Cu(OH)2 is a basic hydroxide and remains insoluble as a characteristic blue precipitate, allowing both the identification and separation of Cu2+ in one step, matching option (c).