JEE Mains Chemistry Past PapershardMCQ SINGLE

Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water. HowJEE Mains Chemistry Past Papers Chemistry Question

Question

Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water. However, the reaction is spontaneous at boiling point of water. Choose the correct option. (A) Both H and S are (–ve) (B) Both H and S are (+ve) (C) H is (–ve) but S is (+ve) (D) H is (+ve) but S is (–ve)

Answer: B

💡 Solution & Explanation

Case I Case II At freezing point At boiling point G > 0 G < 0 H – TS > 0 H –ThS < 0  H > 0 & S < 0

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