JEE Mains Chemistry Past PapershardMCQ SINGLE

The compound A, C8H8O2 reacts with acetophenone to form a single product via cross- Aldol condensatiJEE Mains Chemistry Past Papers Chemistry Question

Question

The compound A, C8H8O2 reacts with acetophenone to form a single product via cross- Aldol condensation. The compound A on reaction with conc. NaOH forms a substituted benzyl alcohol as (A) 2-hydroxy acetophenone (B) 4-methyoxy benzaldehyde (C) 4-hydroxy benzylaldehyde (D) 4-methyl benzoic acid

Answer: B

💡 Solution & Explanation

C–H OCH3 O + O aldol-condensation (A) CH=CH–C–Ph OCH3 O (B) conc.NaOH NaOH  CH2–OH OCH3 (Alcohol) + COO OCH3 Cannizaro reaction Ph (Single Structure) (On cross aldol reaction, a single structure is obtained but it can show geometrical isomerism).

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