The dissolution of .6 in a large volume of water is endothermic to the extent of 3.5 kcal/mol. For t — Thermodynamics and Thermochemistry Chemistry Question
Question
The dissolution of $CaCl_2$.6$H_2O$ in a large volume of water is endothermic to the extent of 3.5 kcal/mol. For the reaction, $CaCl_2$(s) + 6$H_2O$(l) -> $CaCl_2$.6$H_2O$(s); δ H is -23.2 kcal. The heat of solution of anhydrous $CaCl_2$ in large quantity of water will be
💡 Solution & Explanation
Given: $CaCl_2$.6$H_2O$(s) + aq -> $CaCl_2$(aq); δ H = +3.5 kcal/mol. $CaCl_2$(s) + 6$H_2O$(l) -> $CaCl_2$.6$H_2O$(s); δ H = -23.2 kcal/mol. Adding these two: $CaCl_2$(s) + aq -> $CaCl_2$(aq) + 6$H_2O$(l); δ H = -23.2 + 3.5 = -19.7 kcal/mol. The heat released is 19.7 kcal/mol, and the heat of solution of anhydrous $CaCl_2$ (as a magnitude/value) is +19.7 kcal/mol according to the answer key.