When B2H6 is allowed to react with following lewis bases, then how many given lewis bases form adduc β p Block Elements Chemistry Question
Question
When B2H6 is allowed to react with following lewis bases, then how many given lewis bases form adduct through symmetrical cleavage of B2H6 ?<br>NH3, MeNH2, Pyridine, CO, T.H.F., PH3, PF3, Me3N, Me2NH
π‘ Solution & Explanation
Step 1: According to Fajans' rules, covalent character in ionic compounds increases with the size of the anion due to increased polarizability of the larger anion. Step 2: The size of the halide anions increases in the order: F- < Cl- < Br- < I-. This means polarizability increases, thereby increasing covalent character and decreasing ionic character from fluoride to iodide. Step 3: Thus, the decreasing order of ionic character is PbF2 > PbCl2 > PbBr2 > PbI2, matching option (a).