There are five species P, Q, R, S and T. Spectroscopical analysis shows that P, Q and R are homonucl β Chemical Bonding Chemistry Question
Question
There are five species P, Q, R, S and T. Spectroscopical analysis shows that P, Q and R are homonuclear diatomic species and have their bond order 2.5, 1.5 and 2.5 respectively and rest two species S and T are heteronuclear diatomic species and have bond order 3 and 2 respectively. All homonuclear diatomic species are paramagnetic and all heteronuclear diatomic species are diamagnetic in nature. P, R, S and T are monovalent positive ion and Q is monovalent negative ion :
π‘ Solution & Explanation
Step 1: Understand that the potential energy of a bonding system reaches a minimum at the optimum internuclear distance (bond length), balancing attractions and repulsions. Step 2: If the internuclear distance is decreased below this optimum distance, the nuclei and core electron clouds are forced too close together. Step 3: This leads to a massive, steep increase in potential energy due to the sharp increase in electrostatic repulsions between the positively charged nuclei and between the negatively charged electron clouds.