Chemical BondinghardMCQ SINGLE

Arrange the following bonds according to their average bond energies in descending order: C − Cl, C Chemical Bonding Chemistry Question

Question

Arrange the following bonds according to their average bond energies in descending order: C − Cl, C − Br, C − F, C − I (A) C − Cl > C − Br > C − I > C − F (B) C – Br > C – I > C – Cl > C − F (C) C – I > C – Br > C – Cl > C − F (D) C – F > C – Cl > C – Br > C − I

Answer: D) C – F > C – CL > C – BR > C − I

💡 Solution & Explanation

In C − F there is 2p − 2p overlapping involved, in C − Cl the overlapping involved is 2p − 3p whereas for C − Br and C − I the overlappings involved are 2p − 4p and 2p − 5p, respectively. The bond length for the various type of overlappings can be given as: 2p − 2p < 2p − 3p < 2p − 4p < 2p − 5p. As we know that Bond energy The order of bond energy comes out: C − F > C − Cl > C − Br > C − I

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