Select the correct code regarding total number of space isomers for the following compounds :<br>(I) β Coordination Compounds Chemistry Question
Question
Select the correct code regarding total number of space isomers for the following compounds :<br>(I) [Ma3b2c]^n+/-<br>(II) [M(AB)3]^n+/-<br>(III) [Ma2b2c2]^n+/-
Answer: D
π‘ Solution & Explanation
Step 1: Identify that all three complexes are octahedral and coordinated by strong-field ligands (CN^- and NO2^-) which force the pairing of d-electrons. Step 2: Pairing leaves the two inner 3d orbitals (d_x^2-y^2 and d_z^2) completely vacant to participate in hybridization. Step 3: Consequently, all three complexes undergo low-spin inner-orbital d^2sp^3 hybridization, making option (d) the correct answer.
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