JEE Mains Chemistry Past PapershardMCQ SINGLE

Decomposition of A is a first order reaction at T(K) and is given by A(g) B(g) + C(g). In a closed 1JEE Mains Chemistry Past Papers Chemistry Question

Question

Decomposition of A is a first order reaction at T(K) and is given by A(g) B(g) + C(g). In a closed 1 L vessel, 1 bar A(g) is allowed to decompose at T(K). After 100 minutes, the total pressure was 1.5 bar. What is the rate constant (in min –1) of the reaction ? (log 2 = 0.3) (A) 6.9 × 10 –1 (B) 6.9 × 10 –3 (C) 6.9 × 10 –2 (D) 6.9 × 10 –4

Answer: B

💡 Solution & Explanation

Ag  Bg + Cg 1 – – 1–P P P Ptotal = 1 + P 1.5 = 1 + P P = 0.5 1 K ln 0.5  = 0.693 = 6.9 × 10 –3 min –1

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