BX3 + NH3 BX3.NH3 + Heat of adduct formation (H)<br>The numerical value of H is found to be maximum β p Block Elements Chemistry Question
Question
BX3 + NH3 $\xrightarrow{\text{R.T.}}$ BX3.NH3 + Heat of adduct formation ($\Delta$H)<br>The numerical value of $\Delta$H is found to be maximum for :
Answer: D
π‘ Solution & Explanation
Step 1: Note that under anhydrous conditions, aluminium chloride exists as a covalent dimer, Al2Cl6. Step 2: Upon dissolving in water, the hydration of the aluminum center causes ionic dissociation. Step 3: According to the specific textbook solution key, this dissociation is represented by the formation of complex ions [AlCl2(H2O)4]+ and [AlCl4(H2O)2]-, matching option (c).
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