Select correct statement about hydrolysis of BCl3 and NCl3 : — Chemical Bonding Chemistry Question

💡 Solution & Explanation

Step 1: Contrast the mechanisms of hydrolysis for BCl3 and NCl3. Step 2: For BCl3, water attacks the vacant p-orbital of Boron, yielding B(OH)3 and releasing hydrochloric acid (HCl). For NCl3, due to the high electronegativity of Nitrogen relative to Chlorine, Nitrogen carries a partial negative charge and Chlorine carries a partial positive charge. Water attacks the chlorine atom, yielding NH3 and hypochlorous acid (HOCl). Step 3: Thus, NCl3 yields HOCl while BCl3 yields HCl, matching option (c).