Fe(CN)2↓ + 4KCN -> K4[Fe(CN)6] — Redox Reactions and Volumetric Analysis Chemistry Question

💡 Solution & Explanation

Step 1: Identify the reactants. Ferrous cyanide, Fe(CN)2↓, is an insoluble yellowish-brown precipitate. Step 2: Observe the addition of potassium cyanide (KCN). Cyanide acts as a very strong ligand and coordinates with iron(II) to form the highly stable, water-soluble complex potassium ferrocyanide (K4[Fe(CN)6]). Step 3: Since the solid precipitate dissolves upon complexation to form a clear soluble solution, this is a precipitate dissolution reaction (type B). Thus, the correct option is (b).