Which of the following halides cannot be hydrolysed at room temperature?<br>(I) TeF6<br>(II) SF6<br> β p Block Elements Chemistry Question
Question
Which of the following halides cannot be hydrolysed at room temperature?<br>(I) TeF6<br>(II) SF6<br>(III) NCl3<br>(IV) NF3<br>Choose the correct code:
π‘ Solution & Explanation
Step 1: Glass is primarily composed of silica (SiO2) and silicates, which are generally chemically inert to most acids. Step 2: Hydrofluoric acid (HF) is highly unique because it reacts readily with silica to form soluble hexafluorosilicic acid and gaseous silicon tetrafluoride: SiO2 + 4HF -> SiF4 + 2H2O, and SiF4 + 2HF -> H2SiF6. This corrosive action dissolves the glass surface, a process known as glass etching. Step 3: Consequently, HF is the acid used for making permanent markings on glass surfaces. Thus, the correct option is (b).