JEE Mains Chemistry Past PapershardMCQ SINGLE

Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a certain pressJEE Mains Chemistry Past Papers Chemistry Question

Question

Two vessels A and B are connected via stopcock. The vessel A is filled with a gas at a certain pressure. The entire assembly is immersed in water and is allowed to come to thermal equilibrium with water. After opening the stopcock the gas from vessel A expands into vessel B and no change in temperature is observed in the thermometer. Which of the following statement is true ? (A) dw 0 (B) dU 0 (C) The pressure in the vessel B before opening the stopcock is zero (D) dq 0

Answer: C

💡 Solution & Explanation

No gas in vessel B initially  pressure in the vessel B before opening the stopcock is zero. dw < 0 (expansion), dU = 0 (isothermal) So dq > 0 (from 1st law).

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