Which of the following ligand does not as -acid ligand ? β Coordination Compounds Chemistry Question
Question
Which of the following ligand does not as $\pi$-acid ligand ?
Answer: D
π‘ Solution & Explanation
Step 1: Identify that CN^-, CO, and NO^+ are 14-electron isoelectronic species (CN^- = 6+7+1 = 14; CO = 6+8 = 14; NO^+ = 7+8-1 = 14). Step 2: According to molecular orbital (MO) theory, any 14-electron diatomic species has a bond order of 3.0 with all electrons paired in the molecular orbitals. Step 3: Consequently, all three species are diamagnetic and possess a bond order of three, matching option (a).
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