Match the following:<br><br>Column I (Reaction):<br>(A) (g) + (g) → 2(g)<br>(B) 2(g) + (g) → 2(g)<br — Thermodynamics and Thermochemistry Chemistry Question
Question
Match the following:<br><br>Column I (Reaction):<br>(A) $H_2$(g) + $Cl_2$(g) → 2$HCl$(g)<br>(B) 2$N_2O$(g) + $O_2$(g) → 2$NO_2$(g)<br>(C) $H_2$(g) + $I_2$(s) → 2$HI$(g)<br>(D) $N_2$(g) + 3$H_2$(g) → 2$NH_3$(g)<br><br>Column II (Relation):<br>(P) ΔH = ΔU + RT<br>(Q) ΔH = ΔU<br>(R) ΔH = ΔU - 2RT<br>(S) ΔH = ΔU - RT
Answer: A→Q; B→S; C→P; D→R
💡 Solution & Explanation
Evaluated using ΔH = ΔU + Δng × R × T:<br>(A) Δng = 0 → ΔH = ΔU (Q).<br>(B) Δng = -1 → ΔH = ΔU - RT (S).<br>(C) Δng = +1 (as $I_2$ is solid) → ΔH = ΔU + RT (P).<br>(D) Δng = -2 → ΔH = ΔU - 2RT (R).
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