JEE Mains Chemistry Past PapershardMCQ SINGLE

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, …….JEE Mains Chemistry Past Papers Chemistry Question

Question

Consider the hypothetical situation where the azimuthal quantum number, l, takes values 0, 1, 2, ……..n + 1, where n is the principal quantum number. Then, the element with atomic number: (A) 6 has a 2p-valence subshell (B) 9 is the first alkali metal (C) 8 is the first noble gas (D) 13 has a half-filled valence subshell

Answer: C

💡 Solution & Explanation

For n = 1 value of  = 0, 1, 2 For n = 2 value of  = 0, 1, 2, 3 So, according to n + l rule the filling order of subshells will be: 1s 1p 2s 1d 2p 3s 2d 3p 4s …….. (1) 1st noble gas will have configuration 1s2 1p6 so atomic number will be 8. (2) 1st alkali metal will have electronic configuration  1s1  (Z = 1) (3) Electronic configuration of C (Z = 6)  1s2 1p4 (4) Z = 13, Electronic configuration = 1s2 1p6 2s2 1d3 So it will not have half-filled electronic configuration. | JEE MAIN-2020 | DATE : 03-09-2020 (SHIFT-2) | PAPER-2 | OFFICIAL PAPER | CHEMISTRY PAGE # 5

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