Statement I: A fractional-order reaction must be a complex reaction. Statement II: Fractional order β Chemical Kinetics Chemistry Question
Question
Statement I: A fractional-order reaction must be a complex reaction. Statement II: Fractional order of rate-determining step equals to overall order of a complex reaction.
Answer: C
π‘ Solution & Explanation
Statement I is correct because elementary reactions can only have integer molecularity and hence integer orders. Statement II is incorrect because the overall order of a complex reaction is derived from the rate-determining step and any prior fast equilibrium steps, not just simply equal to a simple fractional order of that step.
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