Two moles of an ideal gas ( = 1.5 R) is subjected to the following changes in states: A (500 K, 5 ba β Thermodynamics and Thermochemistry Chemistry Question
Question
Two moles of an ideal gas ($C_{v,m}$ = 1.5 R) is subjected to the following changes in states: A (500 K, 5 bar) β Reversible Isothermal Expansion β B β Isochoric Cooling β C (250 K, 1 bar) β Single stage adiabatic compression β D (3 bar). The correct statement(s) is/are:
π‘ Solution & Explanation
State A: T_A=500K, P_A=5bar, V_A=nRT_A/P_A=200R. B: isothermal so T_B=500K. C: isochoric from B, T_C=250K, P_C=1bar, V_C=nRT_C/P_C=500R=V_B. P_B=nRT_B/V_B=2*R*500/500R=2bar (A correct). D: adiabatic against P_ext=3bar; n*$C_v$*(T_D-250)=-3*(2/3*R*T_D-500R) => 3*(T_D-250)=-2T_D+1500 => 5T_D=2250 => T_D=450K (B correct). Ξ H_CD=n*$C_p$*dT=2*2.5R*(450-250)=1000R (C correct). Ξ U_BC=2*1.5R*(250-500)=-750R (D incorrect).