CrCl3 -NH4Cl/NH4OH-> (A) -Na2O2/H2O-> (B) -Lead acetate-> (C). In this reaction sequence, the compou β Qualitative and Quantitative Analysis Chemistry Question
Question
CrCl3 -NH4Cl/NH4OH-> (A) -Na2O2/H2O-> (B) -Lead acetate-> (C). In this reaction sequence, the compound (C) is:

Answer: D
π‘ Solution & Explanation
Step 1: Adding NH4Cl and NH4OH to CrCl3 precipitates chromium(III) as a green gelatinous hydroxide, Cr(OH)3 (compound A). Step 2: Reacting Cr(OH)3 with sodium peroxide (Na2O2) in water oxidizes the Cr(III) to Cr(VI), forming a yellow solution of sodium chromate, Na2CrO4 (compound B). Step 3: When lead acetate is added to the sodium chromate solution, it forms a bright yellow precipitate of lead chromate, PbCrO4 (compound C). Thus, option (d) is the correct answer.
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