The critical constants Pc and Tc for four gases are Gas Critical temp Critical press 153 K 50 bar 41 β States of Matter and Gaseous State Chemistry Question
Question
The critical constants Pc and Tc for four gases are Gas Critical temp Critical press $O_2$ 153 K 50 bar $Cl_2$ 417 K 76 bar $H_2$ 33.9 K 13.5 bar He 5.12 K 2.2 bar The gas with smallest value of van der Waal's constant b is
Answer: D
π‘ Solution & Explanation
b is directly β V_c = 3b => b = (1/8) * R * T_c / P_c. The ratio T_c / P_c for He is 5.12 / 2.2 = 2.32, which is the smallest among all. Thus, He has the smallest value of b .
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