Given that: C(s) + (g) -> (g); δ H° = -X kJ and 2(g) + (g) -> 2(g); δ H° = -Y kJ. The enthalpy of fo — Thermodynamics and Thermochemistry Chemistry Question
Question
Given that: C(s) + $O_2$(g) -> $CO_2$(g); δ H° = -X kJ and 2$CO$(g) + $O_2$(g) -> 2$CO_2$(g); δ H° = -Y kJ. The enthalpy of formation of carbon monoxide will be
Answer: B
💡 Solution & Explanation
We want the formation of $CO$: C(s) + 1/2 $O_2$(g) -> $CO$(g). Let's use the given reactions: (1) C(s) + $O_2$(g) -> $CO_2$(g); δ H1 = -X. (2) $CO$(g) + 1/2 $O_2$(g) -> $CO_2$(g); δ $H_2$ = -Y/2 (by dividing the second given equation by 2). Subtracting (2) from (1): C(s) + 1/2 $O_2$(g) -> $CO$(g); δ H = δ H1 - δ $H_2$ = -X - (-Y/2) = (Y - 2X)/2.
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