For two gases, A and B with molecular weights MA and MB, it is observed that at a certain temperatur β States of Matter and Gaseous State Chemistry Question
Question
For two gases, A and B with molecular weights MA and MB, it is observed that at a certain temperature, T, the mean velocity of A is equal to the root mean square velocity of B. Thus the mean velocity of A can be made equal to the mean velocity of B, if
π‘ Solution & Explanation
at temperature t: mean velocity of a is c_a = β(8rt / Οm_a), and rms velocity of b is u_b = β(3rt / m_b). given c_a = u_b at temperature t: 8rt/Οm_a = 3rt/m_b β m_b/m_a = 3Ο/8 β 1.18. to make the mean velocities of a and b equal: c_a' = c_b' β t_a' / m_a = t_b' / m_b β t_a' / t_b' = m_a / m_b = 8 / (3Ο) < 1. if b is kept at t, then a must be at a lower temperature t' < t.