Choose the correct option? (A) Electrochemical reactions reverse the action of electrolysis. Whereas β AITS & Test Series Chemistry Question
Question
Choose the correct option? (A) Electrochemical reactions reverse the action of electrolysis. Whereas electrolysis converts electrical energy to chemical energy, electrochemical reactions convert chemical energy directly to electrical energy. (B) There is a convenient difference between electrochemical reactions and chemical reactions: the Gibbs energy change for an electrochemical reaction is equivalent to the maximum electrical work done by system on surrounding. (C) The purpose of the salt bridge is to complete the electrical circuit between the two solutions and to facilitate the movement of ions from one compartment to the other. (D) An equation relating the emf of a cell to variables such as temperature and the concentrations of reacting species is known as Nernst equation.

π‘ Solution & Explanation
Process BC : C B B B B C P P P 1 P 2bar T T 500 250 ο½ ο ο½ ο ο½ and ο¨ ο© 1 BC V m C B U n.C T T ο ο½ ο = ο¨ ο© 2 1.5R 250 500 ο΄ ο΄ ο = β750 R Process CD : U w ο ο½ ο¨ ο© 1 V m D C n.C T T ο ο ο¨ ο© ext D C P V V ο½ο ο or, ο¨ ο© D C n 1.5R T T ο΄ ο΄ ο C D D D C nRT nRT P P P ο¦ οΆ ο½ο ο ο§ ο· ο¨ οΈ D T 450K ο ο½ and ο¨ ο© 1 CD P m D C H n.C . T T ο ο½ ο ο¨ ο© 2