H3C-CH2-CH(Br)-CH3 undergoes (i) PPh3 (ii) BuLi (iii) CH3-C(=O)-CH2CH3 -> X + Y, then X undergoes (i — AITS & Test Series Chemistry Question
Question
H3C-CH2-CH(Br)-CH3 undergoes (i) PPh3 (ii) BuLi (iii) CH3-C(=O)-CH2CH3 -> X + Y, then X undergoes (i) RCO3H (ii) PPh3/Δ -> X -> Br2/CCl4 -> Racemic mixture. Which of the following is correct?

Answer: B
💡 Solution & Explanation
3 i PPh ii BuLi C C C Br C C C C C PPh3 C C C O C C C C C C C C C x 3 3 i RCO H ii PPh / C C C H3 H5C2 C2H5 CH3 x 2 Br CH3 C C CH3 H5C2 Br Br C2H5 2 H / Ni CH3 C C CH3 H5C2 H H5C2 H Baeyer 's reagent CH3 C C CH3 H5C2 OH H5C2 OH Optically inactive Optically inactive CH3 C C CH3 Br C2H5 H5C2 Br Racemic mixture C H3 CH3 CH3 C H3 y
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