Statement I: If the intermolecular attraction between gas molecules in a vessel of fixed volume vani β States of Matter and Gaseous State Chemistry Question
Question
Statement I: If the intermolecular attraction between gas molecules in a vessel of fixed volume vanishes at constant temperature, the pressure of gas will increase. Statement II: The speed at which the gas molecules are colliding at the walls will increase on disappearance of attractive forces.
π‘ Solution & Explanation
Intermolecular attractive forces pull molecules together, reducing their impact force on the walls. If these attractions vanish, the molecules strike the walls with full momentum, increasing the pressure (Statement I is correct). However, the average speed of the molecules depends only on temperature and does not change when intermolecular forces disappear. Thus, Statement II is incorrect.