B(OH)3 + NaOH NaBO2 + Na[B(OH)4] + H2O<br>How can this reaction is made to proceed in forward direct β p Block Elements Chemistry Question
Question
B(OH)3 + NaOH $\rightarrow$ NaBO2 + Na[B(OH)4] + H2O<br>How can this reaction is made to proceed in forward direction?
Answer: A
π‘ Solution & Explanation
Step 1: Lead (Pb) exhibits both +2 and +4 oxidation states, but Pb(IV) is highly oxidizing due to the inert pair effect. Step 2: Iodide (I-) has a large size and low electronegativity, making it a very strong reducing agent. Step 3: When Pb(IV) and I- are brought together, a redox reaction occurs where Pb4+ is reduced to Pb2+ and I- is oxidized to I2. Consequently, PbI4 is thermodynamically unstable and does not exist, matching option (b).
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