Read the following short write up and answer subsequent questions based on observations(A) to (J). [ β Qualitative and Quantitative Analysis Chemistry Question
Question
Read the following short write up and answer subsequent questions based on observations(A) to (J). [SEE DIAGRAM] Flowchart summary: AgNO3 -> white ppt. soluble in aq. NH3 + green coloured solution of a compound (A) green coloured solution of a compound (A) --(NaOH in excess)--> coloured ppt. soluble in excess NaOH green coloured solution of a compound (A) --(KOH/H2O2)--> yellow coloured solution (B) yellow coloured solution (B) --(H2SO4)--> orange coloured solution (C) orange coloured solution (C) --(NH4Cl)--> orange coloured solution of compound (D) --(Crystallization, Ξ)--> gas (G) + H2O + Residue (H) gas (G) --(Li, Ξ)--> solid (I) --(H2O)--> gas (J) --(CuSO4(aq))--> deep blue solution (C) in solid state --(KCl + conc. H2SO4)--> red gas (E) --(KOH(aq))--> (B) --(CH3COOH/Pb2+)--> yellow ppt. (F)
![Chemistry diagram for: Read the following short write up and answer subsequent questions based on observations(A) to (J). [SEE DIAGRAM] Flowcha](/_next/image?url=https%3A%2F%2Furywdhpqdpvmqzlenttu.supabase.co%2Fstorage%2Fv1%2Fobject%2Fpublic%2Fquestion-images%2Fvkj%2Fch10_l3_Q001.png&w=1920&q=75)
π‘ Solution & Explanation
Step 1: Separation of iron(III) hydroxide from aluminium hydroxide relies on their difference in amphoteric character. Step 2: Al(OH)3 is amphoteric and dissolves in excess sodium hydroxide (NaOH) to form soluble sodium aluminate (Na[Al(OH)4]), whereas Fe(OH)3 is purely basic and remains insoluble. Step 3: Therefore, adding NaOH solution successfully separates them by dissolving only Al(OH)3, leaving Fe(OH)3 as a precipitate, which matches option (c).