An ideal gas (γ = 1.5) undergoes a change in state such that the magnitude of heat absorbed by the g — Thermodynamics and Thermochemistry Chemistry Question
Question
An ideal gas (γ = 1.5) undergoes a change in state such that the magnitude of heat absorbed by the gas is equal to the magnitude of work done by the gas. The molar heat capacity of the gas in this process is
Answer: B
💡 Solution & Explanation
In a polytropic process PV^n = constant, work done BY the gas is W = nR*dT/(n-1), and heat absorbed is Q = n*C*dT. For Q = W to hold, we require C = R / (n-1). Also, C = $C_v$ + R/(1-n). Given γ = 1.5, $C_v$ = R/(γ - 1) = 2R. Thus, C = 2R - R/(n-1). Equating these two expressions: R/(n-1) = 2R - R/(n-1) => 2*R/(n-1) = 2R => n - 1 = 1 => n = 2. Substituting n=2 back into C gives C = R/(2-1) = R.
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