Select the correct statement(s): β Thermodynamics and Thermochemistry Chemistry Question
Question
Select the correct statement(s):
Answer: B,D
π‘ Solution & Explanation
By definition, for any reversible process, Ξ S_univ = Ξ S_sys + Ξ S_surr = 0 (B correct). For an isolated system, no heat is exchanged, so Ξ S_surr = 0, which means Ξ S_sys = Ξ S_univ = 0 for a reversible process in an isolated system (D correct). Ξ G is only guaranteed zero for reversible processes at constant T and P. Ξ S_sys can be non-zero for a reversible process in a closed system with heat transfer (A and C incorrect).
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