Match the List-I with List-II List-I (Isothermal process for ideal gas system) List-II Work done (Vf — JEE Mains Chemistry Past Papers Chemistry Question
Question
Match the List-I with List-II List-I (Isothermal process for ideal gas system) List-II Work done (Vf > Vi) A. Reversible expansion I. w = 0 B. Free expansion II. w = –nRT ln f i V V C. Irreversible expansion III. w = –pex (Vf – Vi) D. Irreversible compression IV. w = –pex (Vi – Vf) Choose the correct answer from the options given below : (A) A-IV, B-I, C-III, D-II (B) A-IV, B-II, C-III, D-I (C) A-I, B-III, C-II, D-IV (D) A-II, B-I, C-III, D-IV
💡 Solution & Explanation
(A) WRev. = – gas P dV WRev. Isot. Exp. = – nRT ln f i V V (A) (II) (B) Free expansion Wirrev. = – Pext V Pext = 0 W = 0 (B) (I) (C) Irreversible expansion Wirrev. = – Pext V Wirrev. = – Pext (Vf – Vi) (C) (III) (D) Irreversible compression Wirrev. = – Pext V Wirrev. = – Pext (Vi – Vf)