Choose incorrect stability order : (a) [Cu(NH3)4]^2+ < [Cu(en)2]^2+ < [Cu(trien)]^2+ (b) [Fe(H2O)6]^ β Coordination Compounds Chemistry Question
Question
Choose incorrect stability order : (a) [Cu(NH3)4]^2+ < [Cu(en)2]^2+ < [Cu(trien)]^2+ (b) [Fe(H2O)6]^3+ < [Fe(NO2)6]^3- < [Fe(NH3)6]^3+ (c) [Co(H2O)6]^3+ < [Rh(H2O)6]^3+ < [Ir(H2O)6]^3+ (d) [Cr(NH3)6]^1+ < [Cr(NH3)6]^2+ < [Cr(NH3)6]^3+
π‘ Solution & Explanation
Step 1: Check the stability factors: chelation increases stability (a); splitting energy increases stability down a group (c); higher oxidation states are more stable (d). Step 2: For (b), NO2^- is a much stronger field ligand than NH3 on the spectrochemical series, so [Fe(NO2)6]^3- is expected to be more stable than [Fe(NH3)6]^3+. Step 3: Therefore, the stability order given in (b) is incorrect, which makes it the correct option.