The molarity of [Fe(CN)6]^4- ions in a saturated solution of Ag4[Fe(CN)6] if its solubility product — AITS & Test Series Chemistry Question
Question
The molarity of [Fe(CN)6]^4- ions in a saturated solution of Ag4[Fe(CN)6] if its solubility product constant is K_sp ......
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💡 Solution & Explanation
The given functional equation along with the same equation but with x replaced by x 1 1 and x 1 x respectively, yields: 1 1 f x f 1 tan x x 1 x 1 1 x 1 f f tan x 1 x x 1 1 1 f f x tan 1 x 1 x . Adding the first and third equations and subtracting the second gives: 1 1 1 1 x 1 2f x tan x tan tan 1 x x now 1 1 1 tan t tan t = 2 if t > 0 and 2 if t < 0; it follows that for x 0, 1 , 1 1 1 2 f x f 1 x tan x tan x 1 1 1 tan 1 x tan 1 x 1 1 x 1 x tan tan x x 1 3 2 2 2 2 . Thus, 1 1 0 0 3 4 f x dx 2 f x f 1 x dx 2 . and x 1 x 1 1 4. lim f x 4 lim 2 1 1 1 1 x 1 3 tan x tan tan 2 0 1 x x 4 2 2 and 1 1 1 1 x 1 g x 2f(x) tan x tan tan 1 x x 1 1 1 1 1 x g tan tan 1 1 x 1 x x = 1 1 x tan tan 1 x x 1 1 1 1 1 1 1 x 1 x g x g tan tan 1 x tan tan x 1 x x x 1 2 2 {when x (0, 1)}.