Consider the following table :<br>Compound / Enthalpy of formation (kJ mol^-1) / Bond angle (H-C.A.- — p Block Elements Chemistry Question
Question
Consider the following table :<br>Compound / Enthalpy of formation (kJ mol^-1) / Bond angle (H-C.A.-H) / Boiling point (°C)<br>H2O / x1 / y1 / z1<br>H2S / x2 / y2 / z2<br>H2Se / x3 / y3 / z3<br>H2Te / x4 / y4 / z4<br>According to given information the correct order is/are :
💡 Solution & Explanation
Step 1: The boiling points of molecular hydrides depend on the strength of their intermolecular forces. Step 2: HCl, H2S, and PH3 are polar molecules and exhibit dipole-dipole attractions in addition to London dispersion forces. Silane (SiH4) is highly symmetric and completely non-polar. Step 3: Consequently, SiH4 is held together solely by exceptionally weak dispersion forces, giving it the lowest boiling point in the series. Thus, option (d) is correct.