If the Van der Waal's equation for 1 mole of the gas is represented as Z = PV/RT = 1 + B'P + C'P^2 + — States of Matter and Gaseous State Chemistry Question
Question
If the Van der Waal's equation for 1 mole of the gas is represented as Z = PV/RT = 1 + B'P + C'P^2 + ..., in place of Z = PV/RT = 1 + B/V + C/V^2 + ..., the correct relation(s) is/are
Answer: A,C
💡 Solution & Explanation
Expanding the virial equation in terms of P and V gives the relationships between the coefficients: B' = B / RT → B = B' RT. And C' = (C - B^2) / (RT)^2 → C = B^2 + C' (RT)^2.
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