Equal volumes of one molar hydrochloric acid and one molar sulphuric acid are neutralized completely β Thermodynamics and Thermochemistry Chemistry Question
Question
Equal volumes of one molar hydrochloric acid and one molar sulphuric acid are neutralized completely by dilute $NaOH$ solution by which X and Y kcal of heat are liberated, respectively. Which of the following is true?
Answer: B
π‘ Solution & Explanation
Hydrochloric acid ($HCl$) is a monobasic strong acid, releasing 1 mole of H+ per mole of acid. Sulphuric acid ($H_2SO_4$) is a dibasic strong acid, releasing 2 moles of H+ per mole of acid. Since equal volumes and equal molarities are neutralized, $H_2SO_4$ provides twice the moles of H+ compared to $HCl$, resulting in twice the heat of neutralization. Therefore, Y = 2X.
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