o-nitrotoluene is subjected to the following sequence of reactions: o-nitro toluene --Sn/HCl-- (A) --acetic anhydride-- (B) --conc. HNO3, conc. H2SO4-- (C) --KOH(aq)-- (D) --Cl2(1eqv.), 350°C-- (

Question

o-nitrotoluene is subjected to the following sequence of reactions: o-nitro toluene --Sn/HCl--> (A) --acetic anhydride--> (B) --conc. HNO3, conc. H2SO4--> (C) --KOH(aq)--> (D) --Cl2(1eqv.), 350°C--> (E) --1. NaNO2/HCl 0°-5°C, 2. Cu/HCl/Δ--> (F). [Assume that 'A' to 'F' are major organic products] Now, identify the only INCORRECT statement regarding above sequence of reactions:

Prashant Kotian · Accepted Answer

Correct answer: C. NH2 CH3 NHAc CH3 NHAc CH3 O2N NH2 CH3 O2N (A) (B) (C) (D) NH2 H2C O2N Cl Cl H2C Cl O2N (E) (F) AITS-OT-I (Paper-2)-PCM(Sol.)-JEE(Advanced)/2024 FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942 website: www.fiitjee.com 7 Cl H2C Cl O2N (F)   3 AgNO aq   Cl H2C OH O2N   AgCl 1mole     1mole   3 3 2 AgCl 2NH Ag NH Cl     

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