The number of paramagnetic species from the following is__________ 4 CN Ni , CO Ni , β 4] NiCl [ 6 C β JEE Mains Chemistry Past Papers Chemistry Question
Question
The number of paramagnetic species from the following is__________ 4 CN Ni , CO Ni , β 4] NiCl [ 6 CN Fe , 4 ] ) NH ( Cu [ 6 CN Fe and 6 ] ) O H ( Fe [
Answer: .
π‘ Solution & Explanation
S.No. Species E.C. Hybridisation Magnetic character (i) [Ni(CN)4]2β Ni2+ο οο 3d8 dsp2 Diamagnetic (ii) [NiCl4]2β Ni2+ο οο 3d8 sp3 Paramagnetic (iii) [Cu(CN)4]2+ Cu2+ο οο 3d9 dsp2 Paramagnetic (iv) [Cu(CN)4]3β Cu+ο οο 3d10 sp3 Diamagnetic (v) [Fe(CN)6]3β Fe3+ο οο 3d5 d2sp3 Paramagnetic (vi) [Fe(CN)6]4β Fe2+ο οο 3d6 d2sp3 Diamagnetic (vii) [Fe(H2O)6]2+ Fe2+ο οο 3d6 sp3d2 Paramagnetic
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