JEE Mains Chemistry Past PapershardNUMERICAL

The number of paramagnetic species from the following is__________ 4 CN Ni , CO Ni , – 4] NiCl [ 6 CJEE Mains Chemistry Past Papers Chemistry Question

Question

The number of paramagnetic species from the following is__________ 4 CN Ni , CO Ni , – 4] NiCl [ 6 CN Fe , 4 ] ) NH ( Cu [ 6 CN Fe and 6 ] ) O H ( Fe [

Answer: .

💡 Solution & Explanation

S.No. Species E.C. Hybridisation Magnetic character (i) [Ni(CN)4]2– Ni2+3d8 dsp2 Diamagnetic (ii) [NiCl4]2– Ni2+3d8 sp3 Paramagnetic (iii) [Cu(CN)4]2+ Cu2+3d9 dsp2 Paramagnetic (iv) [Cu(CN)4]3– Cu+3d10 sp3 Diamagnetic (v) [Fe(CN)6]3– Fe3+3d5 d2sp3 Paramagnetic (vi) [Fe(CN)6]4– Fe2+3d6 d2sp3 Diamagnetic (vii) [Fe(H2O)6]2+ Fe2+3d6 sp3d2 Paramagnetic

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