The d-orbitals involved in sp^3d^2 or d^2sp^3 hybridisation of the central metal ion are : β Coordination Compounds Chemistry Question
Question
The d-orbitals involved in sp^3d^2 or d^2sp^3 hybridisation of the central metal ion are :
Answer: A,D
π‘ Solution & Explanation
Step 1: In [Co(NH3)6]Cl3, the cobalt is Co^3+, which has a 3d^6 configuration. Step 2: NH3 is a strong-field ligand that forces pairing, giving a low-spin t_2g^6 e_g^0 configuration. Step 3: The CFSE is calculated as: 6 * (-0.4 Ξ_o) + 0 * (0.6 Ξ_o) = -2.4 Ξ_o, matching option (c).
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