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HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Assertion:Formic acid reduces mercuric chloride. Reason: Formic acid is stronger than acetic acid.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Trough which of the following reactions number of carbon atoms can be increased in the chain? (i) Grignard reaction (ii) Cannizzaro’s reaction (iii) Aldol condensation (iv) HVZ reaction Choose the correct option.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Assertion : Acetic acid does not give haloform reaction. Reason : Acetic acid has no -hydrogen.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Assertion : (CH3)3C–COOH does not give HVZ reaction. Reason : It does not have any -hydrogen

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Assertion : p–hydroxybenzoic acid has a lower boiling point than o–hydroxybenzoic acid. Reason : o–hydroxybenzoic acid has intramolecular hydrogen bonding.

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

In the given reaction, H O C H CO O I -> H O C H COOCOCH II -> Identify the product(s) formed in the given reaction. I II

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Benzamide on treatment with POCl3 gives

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Acetamide is treated separately with the following reagents. Which one of these would give methyl amine?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

In the following sequence of reactions: KMnO SOCl H /Pd BaSO Toluene A B C, -> ->-> Carboxylic Acid and Its Derivatives the product C formed will be :

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Benzoyl chloride is prepared from benzoic acid by

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Ethyl Acetate O (i)CH MgBr (excess) (ii) H -> P, the product will be (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Hydrogenation of benzoyl chloride in the presence of Pd-BaSO4 gives

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

The correct order for the acidic character of the following carboxylic acids is

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Which of the following represents the correct order of the acidity in the given compounds?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

In a set of the given reactions, acetic acid yielded a product C. O C H (i) C H MgBr Anh.AlCl (ii) H CH COOH PCl A B C -> -> -> Product C would be (a)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

The correct order of increasing acid strength of the compounds

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Which of the following is correct order of acidity?

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

An enantiomerically pure acid is treated with racemic mixture of an alcohol having one chiral carbon. The ester formed will be

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

The strongest acid among the following is –

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

End product of the following reaction is Cl alc. KOH red p CH CH COOH A B -> -> (a) (b) (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

When CH2 = CH – COOH is reduced with LiAlH , the compound obtained will be:

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

When propionic acid is treated with aqueous sodium bicarbonate, CO2 is liberated. The C of CO2 comes from

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

(a) (b) Carboxylic Acid and Its Derivatives (c) (d)

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Identify the correct order of boiling points of the following compounds

HARDMCQ SINGLEIChO (Chemistry Olympiad)Inorganic ChemistryCarboxylic Acids and Derivatives

Here Z is (a)

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